Is it okay that I write to an NGO's vice president and ask for...?

an interview opportunity?? I've been hoping to work for that organization since senior high. I recently just got my MA and found the org's recruiting entry-level employees. For one job they offered, I really think I could be a nice fit-in.. I therefore sent them my resume, and an autoreply message told me to wait. It's been 2 wks now, and I feel my chance's getting slimmer; yet I don't want to just give up. I feel a strong desire to reach someone real -- can I write to its VP?